In other ties, Serie A champions Juventus face Europa League winners Atletico Madrid and Barcelona take on Olympique Lyonnais.
A round-up of the UEFA Champions League last-16 first leg matches played on Tuesday.
Bundesliga leaders Bayern Munich powered past third-placed Eintracht Frankfurt 4-0 with an impressive display of high-pressing football on Sunday.
A summary of Wednesday's action in the Champions League quarter-finals first leg.
Liverpool's Robertson frustrated by Neymar 'playacting'
Paris St. Germain's unbeaten start to their Ligue 1 season continued on Friday with a comfortable 3-1 win over Rennes at the Parc des Princes that saw Bradley Barcola score twice to keep them top of the standings.
Manchester United's Argentine winger Angel Di Maria is set to have a medical ahead of a proposed transfer to French champions Paris St-Germain a year after arriving at Old Trafford for a British record transfer fee, local media reported on Sunday.
Premier League champions Manchester City were drawn on Thursday with Juventus, Wydad AC and Al Ain in Group G for next year's FIFA Club World Cup in the United States.
Paris St Germain suffered their second defeat of the Ligue 1 season when they lost 2-0 at Toulouse after being reduced to 10 men on Friday.
Zlatan Ibrahimovic struck twice as Paris St Germain made up for their midweek Champions League defeat by crushing Toulouse 5-0 to stretch their Ligue 1 lead to 13 points on Saturday.
PSG's Neymar to undergo ankle surgery, ruled out for rest of season
Mbappe says playing for Real Madrid will complete childhood dream
A late Mauro Icardi strike earned Paris St Germain a last-gasp 2-1 home victory against Olympique Lyonnais with Lionel Messi making limited impact on his Parc des Princes debut on Sunday.
Cristiano Ronaldo hit a hat-trick in Real Madrid's 4-1 Champions League win at Ajax Amsterdam on Wednesday but big spending trio Zenit St Petersburg, Paris St Germain and Manchester City failed to win.
Paris St Germain have what it takes to reach rhe Champions League final this season after three consecutive quarter-final exits, Argentine winner Angel Di Maria said on Friday.
Jose Mourinho will leave Real Madrid at the end of the season after coming to a mutual agreement with the Spanish club three years before the end of his contract, president Florentino Perez said on Monday.
A summary of Saturday's action in the Serie A, Ligue 1 and Bundesliga
The 34-year-old Argentine joined PSG on a two-year contract with the option of extending it by another year after Barcelona made it clear they could not afford to keep him because of LaLiga's financial fair play rules.
Karl-Heinz Rummenigge has become the latest high profile official to urge UEFA to enforce its own Financial Fair Play rules, saying it must act against Paris St Germain if there has been any breach of regulations.
Girona thrash Osasuna for first win of the season
Zlatan Ibrahimovic bid farewell to Paris St Germain in style by scoring twice and setting up another as the French champions completed a second successive domestic treble by beating Olympique de Marseille 4-2 in the French Cup final on Saturday.
Police have launched an investigation after Paris St Germain's players were confronted by angry supporters upon their return to the French capital on Wednesday following their 6-1 Champions League defeat in Barcelona, the Ligue 1 club has said.
Pique and Pedro put Barcelona on top of the La Liga on goal difference with a 3-0 win over Malaga and Atletico Madrid won 4-2 at Rayo Vallecano to stay hot on their heels. Check out the footballers who shone over the weekend.
Paris St Germain, who were declared Ligue 1 champions, are looking to play their Champions League games abroad after the French government said professional sports would not be allowed to return before September.
A summary of the concluding day's action in the German Cup, French Cup and La Liga.
Two goals from Luis Diaz and one from Mohamed Salah helped Liverpool stroll to a 3-0 victory at Manchester United.
Hosts France reached the Olympic men's football semi-finals for the first time in 40 years with a 1-0 win over Argentina thanks to Jean-Philippe Mateta's first-half goal in a grudge match in Bordeaux on Friday.
Zlatan Ibrahimovic scored his 18th goal of the season to inspire Ligue 1 leaders Paris St Germain to a comprehensive 3-0 victory at 10-man Stade Brest which lifted them three points clear at the top on Friday.
Images from Wednesday's Champions League matches, between Real Madrid and Paris St Germain, and Manchester City and Sporting CP
Real Madrid coach Mourinho surprised many by including Kaka in the starting lineup for Wednesday's 4-1 Champions League win at Ajax and he responded with a performance full of verve and creativity that suggests he may be working his way back into contention.
Lionel Messi does not deserve to win the next FIFA Ballon d'Or as he has only won one minor trophy this year, his former Barcelona team mate Zlatan Ibrahimovic said on Tuesday.
Monaco's late Ligue 1 title challenge stalled on Friday when the principality side were held to a 1-1 home draw by St Etienne.
Barca will now visit seventh-placed Osasuna on Saturday before hosting Young Boys in the Champions League next week, when they will look to rebound following a 2-1 loss in their opening match at Monaco.
Olympique Marseille and Paris St Germain supporters clashed on Sunday after their Ligue 1 game was postponed and the whole PSG team quarantined when three players were diagnosed with H1N1 flu.
A summary of Tuesday's Champions League first leg quarter-finals between Arsenal and Real Madrid, and Inter Milan and Bayern Munich.
Paris St Germain would be odds-on certainties to easily beat Chelsea and take a big step towards the Champions League quarter-finals on Tuesday if statistics and domestic form decided matches.
News of all that's transpired on and off the football field
Olympique Lyon's hopes of clinching an eighth consecutive Ligue 1 title suffered another blow when they were held to a goalless draw at home to Paris St Germain on Friday.
Bayern Munich winger Serge Gnabry has been ruled out of Wednesday's Champions League quarter-final first leg against Paris St Germain after testing positive for COVID-19 while midfielder Marc Roca will miss the game due to injury.
Barcelona have been very active in the transfer market in recent years, completing three of the top six most expensive transfers ever.
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